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Published Online: 02 June 2016
Accepted: May 2016
Appl. Phys. Lett. 108, 223901 (2016); https://doi.org/10.1063/1.4953157
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We report the electron discharge effect due to point contact between liquid metal and solid metal particles in electrolyte. Adding nickel particles induces drastic hydrogen generating and intermittent jumping of a sub-millimeter EGaIn droplet in NaOH solution. Observations from different orientations disclose that such jumping behavior is triggered by pressurized bubbles under the assistance of interfacial interactions. Hydrogen evolution around particles provides clear evidence that such electric instability originates from the varied electric potential and morphology between the two metallic materials. The point-contact-induced charge concentration significantly enhances the near-surface electric field intensity at the particle tips and thus causes electric breakdown of the electrolyte.
We thank Professor W. Fu from Technical Institute of Physics and Chemistry, CAS, and Professor W. Chen from China Electric Power Research Institute for their helpful discussions. J.T. acknowledges J. Li for his assistance in AFM measurement. This work was partially supported by the Dean's Research Funding of the Chinese Academy of Sciences.
  1. 1. C. J. Wu, P. Söderlind, J. N. Glosli, and J. E. Klepeis, Nat. Mater. 8, 223 (2009). https://doi.org/10.1038/nmat2375, Google ScholarCrossref
  2. 2. E. Saiz and A. P. Tomsia, Nat. Mater. 3, 903 (2004). https://doi.org/10.1038/nmat1252, Google ScholarCrossref
  3. 3. R. S. Timsit, Appl. Phys. Lett. 40, 379 (1982). https://doi.org/10.1063/1.93109, Google ScholarScitation
  4. 4. M. J. Regan, E. H. Kawamoto, S. Lee, P. S. Pershan, N. Maskil, M. Deutsch, O. M. Magnussen, B. M. Ocko, and L. E. Berman, Phys. Rev. Lett. 75, 2498 (1995). https://doi.org/10.1103/PhysRevLett.75.2498, Google ScholarCrossref
  5. 5. H. Tostmann, E. DiMasi, P. S. Pershan, B. M. Ocko, O. G. Shpyrko, and M. Deutsch, Phys. Rev. B 59, 783 (1999). https://doi.org/10.1103/PhysRevB.59.783, Google ScholarCrossref
  6. 6. L. Bosio, R. Cortes, G. Folcher, and M. Froment, J. Electrochem. Soc. 139, 2110 (1992). https://doi.org/10.1149/1.2221187, Google ScholarCrossref
  7. 7. R. Parsons, Chem. Rev. 90, 813 (1990). https://doi.org/10.1021/cr00103a008, Google ScholarCrossref
  8. 8. J. W. Schultze and M. M. Lohrengel, Electrochim. Acta 45, 2499 (2000). https://doi.org/10.1016/S0013-4686(00)00347-9, Google ScholarCrossref
  9. 9. R. N. Kuklin and V. V. Emets, Prot. Met. Phys. Chem. Surf. 47, 1 (2011). https://doi.org/10.1134/S2070205111010084, Google ScholarCrossref
  10. 10. P. A. Kralchevsky and K. Nagayama, Adv. Colloid Interface 85, 145 (2000). https://doi.org/10.1016/S0001-8686(99)00016-0, Google ScholarCrossref
  11. 11. M. G. Nikolaides, A. R. Bausch, M. F. Hsu, A. D. Dinsmore, M. P. Brenner, C. Gay, and D. A. Weitz, Nature 420, 299 (2002). https://doi.org/10.1038/nature01113, Google ScholarCrossref
  12. 12. J. Zhang, Y. Yao, L. Sheng, and J. Liu, Adv. Mater. 27, 2648 (2015). https://doi.org/10.1002/adma.201405438, Google ScholarCrossref
  13. 13. X. Tang, S. Tang, V. Sivan, W. Zhang, A. Mitchell, K. Kalantar-zadeh, and K. Khoshmanesh, Appl. Phys. Lett. 103, 174104 (2013). https://doi.org/10.1063/1.4826923, Google ScholarScitation
  14. 14. D. Kim, P. Thissen, G. Viner, D. Lee, W. Choi, Y. J. Chabal, and J. B. Lee, ACS Appl. Mater. Inter. 5, 179 (2013). https://doi.org/10.1021/am302357t, Google ScholarCrossref
  15. 15. M. Gong, W. Zhou, M. Tsai, J. Zhou, M. Guan, M. Lin, B. Zhang, Y. Hu, D. Wang, J. Yang, S. J. Pennycook, B. Hwang, and H. Dai, Nat. Commun. 5, 4695 (2014). https://doi.org/10.1038/ncomms5695, Google ScholarCrossref
  16. 16. Y. Yu, Q. Wang, L. Yi, and J. Liu, Adv. Eng. Mater. 16, 255 (2014). https://doi.org/10.1002/adem.201300420, Google ScholarCrossref
  17. 17. E. L. Decker, B. Frank, Y. Suo, and S. Garoff, Colloid Surf., A 156, 177 (1999). https://doi.org/10.1016/S0927-7757(99)00069-2, Google ScholarCrossref
  18. 18. K. Du, E. Glogowski, T. Emrick, T. P. Russell, and A. D. Dinsmore, Langmuir 26, 12518 (2010). https://doi.org/10.1021/la100497h, Google ScholarCrossref
  19. 19. N. Krstajic, M. Popovic, B. Grgur, M. Vojnovic, and D. Sepa, J. Electroanal. Chem. 512, 16 (2001); https://doi.org/10.1016/S0022-0728(01)00590-3, Google ScholarCrossref
    N. Krstajic , M. Popovic , B. Grgur , M. Vojnovic , and D. Sepa, J. Electroanal. Chem. 512, 27 (2001). https://doi.org/10.1016/S0022-0728(01)00591-5, , Google ScholarCrossref
  20. 20. J. F. Kolb, R. P. Joshi, S. Xiao, and K. H. Schoenbach, J. Phys. D 41, 234007 (2008). https://doi.org/10.1088/0022-3727/41/23/234007, Google ScholarCrossref
  21. 21. L. E. Gonzalez, D. J. Gonzalez, and M. J. Stott, J. Chem. Phys. 123, 201101 (2005). https://doi.org/10.1063/1.2125728, Google ScholarScitation
  22. 22. W. Schmickler and D. Henderson, J. Chem. Phys. 80, 3381 (1984); https://doi.org/10.1063/1.447092, Google ScholarScitation
    W. Schmickler and D. Henderson, J. Chem. Phys. 85, 1650 (1986). https://doi.org/10.1063/1.451819, , Google ScholarScitation, ISI
  23. 23. K. B. Oldham, J. Electroanal. Chem. 613, 131 (2008). https://doi.org/10.1016/j.jelechem.2007.10.017, Google ScholarCrossref
  24. 24. P. Brüesch and T. Christen, J. Appl. Phys. 95, 2846 (2004). https://doi.org/10.1063/1.1641517, Google ScholarScitation
  25. 25. I. I. Diakonov, G. S. Pokrovski, P. Benezeth, J. Schott, J. Dandurand, and J. Escalier, Geochim. Cosmochim. Act. 61, 1333 (1997). https://doi.org/10.1016/S0016-7037(97)00011-2, Google ScholarCrossref
  26. 26. I. W. McAllister, J. Phys. D 23, 359 (1990). https://doi.org/10.1088/0022-3727/23/3/016, Google ScholarCrossref
  27. 27. V. Kumaran, Phys. Rev. Lett. 85, 4996 (2000). https://doi.org/10.1103/PhysRevLett.85.4996, Google ScholarCrossref
  28. 28. L. Enze, J. Phys. D 19, 1 (1986). https://doi.org/10.1088/0022-3727/19/1/005, Google ScholarCrossref
  29. 29. V. S. Bagotsky, Fundamentals of Electrochemistry ( Wiley, New Jersy, 2006). Google Scholar
  30. 30. B. J. Kirby, Micro- and Nanoscale Fluid Mechanics: Transport in Microfluidic Devices ( Cambridge University Press, New York, 2010). Google ScholarCrossref
  31. 31. L. F. Kozin and A. V. Gaidin, Russ. J. Appl. Chem. 82, 406 (2009). https://doi.org/10.1134/S1070427209030124, Google ScholarCrossref
  32. 32. M. D. Arning and S. D. Minteer, Handbook of Electrochemistry, edited by C. G. Zoski ( Elsevier, Amsterdam, 2007). Google Scholar
  33. 33. J. N. Butler and M. L. Meehan, J. Phys. Chem. 70, 3582 (1966). https://doi.org/10.1021/j100883a037, Google ScholarCrossref
  34. 34. N. B. Morley, J. Burris, L. C. Cadwallader, and M. D. Nornberg, Rev. Sci. Instrum. 79, 056107 (2008). https://doi.org/10.1063/1.2930813, Google ScholarScitation
  35. 35. J. B. Hasted, D. M. Ritson, and C. H. Collie, J. Chem. Phys. 16, 1 (1948). https://doi.org/10.1063/1.1746645, Google ScholarScitation, ISI
  36. 36. The increment of mole number of the hydrogen molecule after a time interval dt equals to dN=(1c)idt/2F. And the pressure increment of an individual bubble (bubble j) at the bubble base is dP=RTdN/V. Then the growth rate of fj becomes dfj/dt=AdP/dt=[(1c)ART/2FV]i. The vector sum of fj, i.e., F, is of the same scale with fj. Google Scholar
  37. 37. In the calculation, the SMP is assumed to be spherical and its diameter is taken to be 5μm. c is taken to be 0.5. Based on the experimental observation, A is taken to be 1/6 of the surface area of the LMD ( 480μm in diameter) and V is 1/3 of its volume, respectively. Google Scholar
  38. 38. K. Du, E. Glogowski, M. T. Tuominen, T. Emrick, T. P. Russell, and A. D. Dinsmore, Langmuir 29, 13640 (2013). https://doi.org/10.1021/la403263z, Google ScholarCrossref
  39. 39. H. Mizes, M. Ott, E. Eklund, and D. Hays, Colloid Surf., A 165, 11 (2000). https://doi.org/10.1016/S0927-7757(99)00442-2, Google ScholarCrossref
  40. 40. B. Gady, D. Schleef, R. Reifenberger, D. Rimai, and L. P. DeMejo, Phys. Rev. B 53, 8065 (1996). https://doi.org/10.1103/PhysRevB.53.8065, Google ScholarCrossref
  41. 41. See supplementary material at http://dx.doi.org/10.1063/1.4953157 for results of the tests on different combinations. Google Scholar
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