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Published Online: 07 August 2013
Accepted: July 2013

A new perspective on correlated polyelectrolyte adsorption: Positioning, conformation, and patterns

J. Chem. Phys. 139, 054906 (2013); https://doi.org/10.1063/1.4817338
Sandra C. C. Nunesa), Tânia F. G. G. Cova, and A. A. C. C. Pais
more...View Affiliations
Abstract
This work focuses on multiple chain deposition, using a coarse-grained model. The phenomenon is assessed from a novel perspective which emphasizes the conformation and relative arrangement of the deposited chains. Variations in chain number and length are considered, and the surface charge in the different systems ranges from partially neutralized to reversed by backbone deposition. New tools are proposed for the analysis of these systems, in which focus is given to configuration-wise approaches that allow the interpretation of correlated multi-chain behavior. It is seen that adsorption occurs, with a minimal effect upon the bulk conformation, even when overcharging occurs. Also, chain ends create a lower electrostatic potential, which makes them both the least adsorbed region of the backbone, and the prevalent site of closer proximity with other chains. Additionally, adsorption into the most favorable region of the surface overrides, to a large degree, interchain repulsion.

ACKNOWLEDGMENTS

This work was supported by FEDER funds through the COMPETE program—Programa Operacional Factores de Competitividade—and by National funds through Fundação para a Ciência e Tecnologia(FCT) under the Project PTDC/QUI-QUI/101442/2008 (COMPETE: FCOMP-01-0124-FEDER-010831). T.F.G.G.C. acknowledges the same project for a B.I. research grant. S.C.C.N. gratefully acknowledges the post-doctoral research Grant No. SFRH/BPD/71683/2010 assigned by the Fundação para a Ciência e Tecnologia (FCT).

REFERENCES

  1. 1. A. S. Malinin, I. V. Kalashnikova, A. A. Rakhnyanskaya, and A. A. Yaroslavov, Polym. Sci., Ser. A 54, 81–86 (2012). https://doi.org/10.1134/S0965545X1201004X , Google ScholarCrossref
  2. 2. D. L. Elbert, C. B. Herbert, and J. A. Hubbell, Langmuir 15, 5355–5362 (1999). https://doi.org/10.1021/la9815749 , Google ScholarCrossref
  3. 3. M. Dimitrova, Y. Arntz, P. Lavalle, F. Meyer, M. Wolf, C. Schuster, Y. Haïkel, J.-C. Voegel, and J. Ogier, Adv. Funct. Mater. 17, 233–245 (2007). https://doi.org/10.1002/adfm.200600155 , Google ScholarCrossref
  4. 4. N. Benkirane-Jessel, P. Schwinte, P. Falvey, R. Darcy, Y. Haikel, P. Schaaf, J. C. Voegel, and J. Ogier, Adv. Funct. Mater. 14, 174–182 (2004). https://doi.org/10.1002/adfm.200304413 , Google ScholarCrossref
  5. 5. F. Caruso, K. Niikura, D. N. Furlong, and Y. Okahata, Langmuir 13, 3422–3426 (1997). https://doi.org/10.1021/la960821a , Google ScholarCrossref
  6. 6. F. Caruso, K. Niikura, D. N. Furlong, and Y. Okahata, Langmuir 13, 3427–3433 (1997). https://doi.org/10.1021/la9608223 , Google ScholarCrossref
  7. 7. F. Caruso, E. Rodda, D. F. Furlong, K. Niikura, and Y. Okahata, Anal. Chem. 69, 2043–2049 (1997). https://doi.org/10.1021/ac961220r , Google ScholarCrossref
  8. 8. Y. Wang, L. Hosta-Rigau, H. Lomas, and F. Caruso, Phys. Chem. Chem. Phys. 13, 4782–4801 (2011). https://doi.org/10.1039/c0cp02287j , Google ScholarCrossref
  9. 9. M. I. Toral, J. González-Navarrete, A. Leiva, H. E. Ríos, and M. D. Urzúa, Eur. Polym. J. 45, 730–737 (2009). https://doi.org/10.1016/j.eurpolymj.2008.12.011 , Google ScholarCrossref
  10. 10. L. Wagberg, L. Winter, L. Odberg, and T. Lindstrom, Colloids Surf. 27, 163–173 (1987). https://doi.org/10.1016/0166-6622(87)80140-3 , Google ScholarCrossref
  11. 11. D. Volodkin, Y. Arntz, P. Schaaf, H. Moehwald, J.-C. Voegel, and V. Ball, Soft Matter 4, 122–130 (2008). https://doi.org/10.1039/b713563g , Google ScholarCrossref
  12. 12. H. Kerdjoudj, N. Berthelemy, F. Boulmedais, J.-F. Stoltz, P. Menu, and J. C. Voegel, Soft Matter 6, 3722–3734 (2010). https://doi.org/10.1039/b920729e , Google ScholarCrossref
  13. 13. F. Zhou and W. T. S. Huck, Phys. Chem. Chem. Phys. 8, 3815–3823 (2006). https://doi.org/10.1039/b606415a , Google ScholarCrossref
  14. 14. S. M. Notley, J. Colloid Interface Sci. 375, 35–40 (2012). https://doi.org/10.1016/j.jcis.2012.02.060 , Google ScholarCrossref
  15. 15. G. Decher, Science 277, 1232–1237 (1997). https://doi.org/10.1126/science.277.5330.1232 , Google ScholarCrossref
  16. 16. Y.-C. Chang and C. W. Frank, Langmuir 12, 5824–5829 (1996). https://doi.org/10.1021/la950686m , Google ScholarCrossref
  17. 17. Y. Wang, Q. Hong, Y. Chen, X. Lian, and Y. Xiong, Colloids Surf., B 100, 77–83 (2012). https://doi.org/10.1016/j.colsurfb.2012.05.030 , Google ScholarCrossref
  18. 18. A. G. Cherstvy and R. G. Winkler, Phys. Chem. Chem. Phys. 13, 11686–11693 (2011). https://doi.org/10.1039/c1cp20749k , Google ScholarCrossref
  19. 19. M. Manghi and M. Aubouy, Phys. Chem. Chem. Phys. 10, 1697–1706 (2008). https://doi.org/10.1039/b716014c , Google ScholarCrossref
  20. 20. E. Seyrek, J. Hierrezuelo, A. Sadeghpour, I. Szilagyi, and M. Borkovec, Phys. Chem. Chem. Phys. 13, 12716–12719 (2011). https://doi.org/10.1039/c1cp20654k , Google ScholarCrossref
  21. 21. A. G. Cherstvy and R. G. Winkler, J. Phys. Chem. B 116, 9838–9845 (2012). https://doi.org/10.1021/jp304980e , Google ScholarCrossref
  22. 22. R. Messina, Macromolecules 37, 621–629 (2004). https://doi.org/10.1021/ma034689e , Google ScholarCrossref
  23. 23. C. F. Narambuena, D. M. Beltramo, and E. P. M. Leiva, Macromolecules 40, 7336–7342 (2007). https://doi.org/10.1021/ma0705568 , Google ScholarCrossref
  24. 24. J.-M. Y. Carrillo and A. V. Dobrynin, Langmuir 23, 2472–2482 (2007). https://doi.org/10.1021/la063079f , Google ScholarCrossref
  25. 25. C. Y. Kong and M. Muthukumar, J. Chem. Phys. 109, 1522–1527 (1998). https://doi.org/10.1063/1.476703 , Google ScholarScitation
  26. 26. Q. Wang, Soft Matter 5, 413–424 (2009). https://doi.org/10.1039/b809095e , Google ScholarCrossref
  27. 27. B. Qiao, J. J. Cerdà, and C. Holm, Macromolecules 44, 1707–1718 (2011). https://doi.org/10.1021/ma1026109 , Google ScholarCrossref
  28. 28. R. R. Netz and J.-F. Joanny, Macromolecules 32, 9013–9025 (1999). https://doi.org/10.1021/ma990263h , Google ScholarCrossref
  29. 29. M. Schönhoff, J. Phys.: Condens. Matter 15, R1781–R1808 (2003). https://doi.org/10.1088/0953-8984/15/49/R01 , Google ScholarCrossref
  30. 30. P. A. Patel, J. Jeon, P. T. Mather, and A. V. Dobrynin, Langmuir 22, 9994–10002 (2006). https://doi.org/10.1021/la061658e , Google ScholarCrossref
  31. 31. B. Qiao, M. Sega, and C. Holm, Phys. Chem. Chem. Phys. 13, 16336–16342 (2011). https://doi.org/10.1039/c1cp21777a , Google ScholarCrossref
  32. 32. C. F. Narambuena, D. M. Beltramo, and E. P. M. Leiva, Macromolecules 41, 8267–8274 (2008). https://doi.org/10.1021/ma800325e , Google ScholarCrossref
  33. 33. R. Messina, Phys. Rev. E 70, 051802 (2004). https://doi.org/10.1103/PhysRevE.70.051802 , Google ScholarCrossref
  34. 34. C. N. Patra, R. Chang, and A. Yethiraj, J. Phys. Chem. B 108, 9126–9132 (2004). https://doi.org/10.1021/jp0373200 , Google ScholarCrossref
  35. 35. R. S. Dias, A. A. C. C. Pais, P. Linse, M. G. Miguel, and B. Lindman, J. Phys. Chem. B 109, 11781–11788 (2005). https://doi.org/10.1021/jp050158b , Google ScholarCrossref
  36. 36. M. Ellis, C. Y. Kong, and M. Muthukumar, J. Chem. Phys. 112, 8723–8729 (2000). https://doi.org/10.1063/1.481474, Google ScholarScitation
  37. 37. W. Fang, Y. Cai, X. Chen, R. Su, T. Chen, N. Xia, L. Li, Q. Yang, J. Han, and S. Han, Bioorg. Med. Chem. Lett. 19, 1903–1907 (2009). https://doi.org/10.1016/j.bmcl.2009.02.059 , Google ScholarCrossref
  38. 38. M. Urzúa, X. Briones, L. P. Carrasco, M. Encinas, and D. Petri, Polymer 51, 3445–3452 (2010). https://doi.org/10.1016/j.polymer.2010.05.054 , Google ScholarCrossref
  39. 39. X. G. Briones, M. V. Encinas, D. F. S. Petri, J. E. Pavez, R. A. T. M. Yazdani-Pedram, and M. D. Urzúa, Langmuir 27, 13524–13532 (2011). https://doi.org/10.1021/la2025632 , Google ScholarCrossref
  40. 40. S. C. C. Nunes, P. Pinto, and A. A. C. C. Pais, J. Comput. Chem. 34, 1198–1209 (2013). https://doi.org/10.1002/jcc.23238 , Google ScholarCrossref
  41. 41. R. Messina, J. Chem. Phys. 124, 014705 (2006). https://doi.org/10.1063/1.2140692 , Google ScholarScitation, ISI
  42. 42. O. V. Borisov, E. B. Zhulina, and T. M. Birshtein, J. Phys. II 4, 913–929 (1994). https://doi.org/10.1051/jp2:1994174 , Google ScholarCrossref
  43. 43. P. Linse, MOLSIM, version 4.0.8, 2004. Google Scholar
  44. 44. M. P. Allen and D. J. Tildesley, Computer Simulation of Liquids (Clarendon, Oxford, 1987). Google Scholar
  45. 45. M. Skepö, J. Chem. Phys. 129, 185101 (2008). https://doi.org/10.1063/1.3002317 , Google ScholarScitation
  46. 46. A. Tulpar and W. A. Ducker, J. Phys. Chem. B 108, 1667–1676 (2004). https://doi.org/10.1021/jp0347668 , Google ScholarCrossref
  47. 47. O. J. Rojas, Encyclopedia of Surface and Colloid Science (Marcel Dekker, 2002), pp. 517–535. Google Scholar
  48. 48. J. W. Eaton, D. Bateman, and S. Hauberg, GNU Octave Manual: A High-level Interactive Language for Numerical Computations (Network Theory Ltd., 2007). Google Scholar
  49. 49. J. Buescu, Ingenium Series II, 129, 110–111 (2012) (in Portuguese). Google Scholar
  50. 50. J. Brunhorn, O. Tenchio, and R. Rojas, RoboCup 2006: Robot Soccer World Cup X, Lecture Notes in Artificial Intelligence Vol. 4434 (Springer-Verlag, Berlin, 2007), pp. 516–522. Google ScholarCrossref
  51. 51. Y. Miao, G. Yan, and Z. Lin, Int. J. Innov. Comput. Inf. and Control 7, 5851–5864 (2011). Google Scholar
  52. 52. M. J. Mossinghoff, J. Comb. Theory, Ser. A 118, 1801–1815 (2011). https://doi.org/10.1016/j.jcta.2011.03.004 , Google ScholarCrossref
  53. 53. A. Webster, Mon. Not. R. Astron. Soc. 353, 1304–1310 (2004). https://doi.org/10.1111/j.1365-2966.2004.08158.x , Google ScholarCrossref
  54. 54. E. Munoz-Sandoval, J. J. Torres-Heredia, and F. Lopez-Urias, J. Appl. Phys. 97, 10E318 (2005). https://doi.org/10.1063/1.1858113 , Google ScholarScitation
  55. 55. H. Ahrens, H. Baltes, J. Schmitt, H. Möhwald, and C. A. Helm, Macromolecules 34, 4504–4512 (2001). https://doi.org/10.1021/ma001520h , Google ScholarCrossref
  56. 56. A. A. Chialvo and J. M. Simonson, J. Phys. Chem. C 112, 19521–19529 (2008). https://doi.org/10.1021/jp8041846 , Google ScholarCrossref
  57. 57. Y. Samoshina, T. Nylander, P. Claesson, K. Schillén, I. Iliopoulos, and B. Lindman, Langmuir 21, 2855–2864 (2005). https://doi.org/10.1021/la047311y , Google ScholarCrossref
  58. 58. P. Linse and N. Källrot, Macromolecules 43, 2054–2068 (2010). https://doi.org/10.1021/ma902338m , Google ScholarCrossref
  59. © 2013 AIP Publishing LLC.

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