No Access Submitted: 15 May 2012 Accepted: 28 July 2012 Published Online: 08 August 2012
Appl. Phys. Lett. 101, 061601 (2012); https://doi.org/10.1063/1.4745780
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  • L. Dong
  • J. Hansen
  • P. Xu
  • M. L. Ackerman
  • S. D. Barber
  • J. K. Schoelz
  • D. Qi
  • P. M. Thibado
Freestanding graphene membranes were functionalized with SnO2 nanoparticles. A detailed procedure providing uniform coverage and chemical synthesis is presented. Elemental composition was determined using scanning electron microscopy combined with energy dispersive x-ray analysis. A technique called electrostatic-manipulation scanning tunneling microscopy was used to probe the electromechanical properties of functionalized freestanding graphene samples. We found ten times larger movement perpendicular to the plane compared to pristine freestanding graphene and propose a nanoparticle encapsulation model.
L.D. acknowledges financial support by the Taishan Overseas Scholar Program, the National Natural Science Foundation of China (51172113), the Shandong Natural Science Foundation (JQ201118), the Research Corporation for Science Advancement, and the National Science Foundation (DMR-0821159). P.X. and P.T. are thankful for the financial support of the Office of Naval Research under Grant No. N00014-10-1-0181 and the National Science Foundation under Grant No. DMR-0855358.
  1. 1. M. Gratzel, Nature (London) 414, 338 (2001). https://doi.org/10.1038/35104607 , Google ScholarCrossref, ISI
  2. 2. Y. Wang, W. Wei, X. Liu, and Y. Gu, Sol. Energy Mater. Sol. Cells 98, 129 (2012). https://doi.org/10.1016/j.solmat.2011.10.003 , Google ScholarCrossref
  3. 3. A. Tang, S. Qu, F. Teng, Y. Hou, Y. Wang, and Z. Wang, J. Nanosci. Nanotechnol. 11, 9384 (2011). https://doi.org/10.1166/jnn.2011.5311 , Google ScholarCrossref
  4. 4. P. W. M. Blom, V. D. Mihailetchi, L. J. A. Koster, and D. E. Markov, Adv. Mater. 19, 1551 (2007). https://doi.org/10.1002/adma.200601093 , Google ScholarCrossref, ISI
  5. 5. V. Sgobba and D. M. Guldi, J. Mater. Chem. 18, 153 (2008). https://doi.org/10.1039/b713798m , Google ScholarCrossref
  6. 6. H. Hoppe and N. S. Sariciftci, J. Mater. Chem. 16, 45 (2006). https://doi.org/10.1039/b510618b , Google ScholarCrossref
  7. 7. H. Imahori, K. Hagiwara, T. Akiyama, M. Aoki, S. Taniguchi, T. Okada, M. Shirakawa, and Y. Sakata, Chem. Phys. Lett. 263, 545 (1996). https://doi.org/10.1016/S0009-2614(96)01244-4 , Google ScholarCrossref
  8. 8. D. M. Guldi, G. M. A. Rahman, V. Sgobba, and C. Ehli, Chem. Soc. Rev. 35, 471 (2006). https://doi.org/10.1039/b511541h , Google ScholarCrossref
  9. 9. M. Balleeswaraiah and D. Lifeng, Mater. Res. Soc. Symp. Proc. 1204, K10–37 (2010). https://doi.org/10.1557/PROC-1204-K10-37 , Google ScholarCrossref
  10. 10. W.-Q. Han and A. Zettl, Nano Lett. 3, 681 (2003). https://doi.org/10.1021/nl034142d , Google ScholarCrossref
  11. 11. T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011). https://doi.org/10.1038/ncomms1464 , Google ScholarCrossref, ISI
  12. 12. J. Liang, W. Wei, D. Zhong, Q. Yang, L. Li, and L. Guo, ACS Appl. Mater. Interfaces 4, 454 (2012). https://doi.org/10.1021/am201541s , Google ScholarCrossref
  13. 13. A. Reina, X. Jia, J. Ho, D. Nezich, H. Son, V. Bulovic, M. S. Dresselhaus, and J. Kong, Nano Lett. 9, 30 (2009). https://doi.org/10.1021/nl801827v , Google ScholarCrossref, ISI
  14. 14. L. Dong, Nanotechnology 20, 465602 (2009). https://doi.org/10.1088/0957-4484/20/46/465602 , Google ScholarCrossref
  15. 15. L. Dong, L. Yu, Z. Cui, H. Dong, P. Ercius, C. Song, and T. Duden, Nanotechnology 23, 035702 (2012). https://doi.org/10.1088/0957-4484/23/3/035702 , Google ScholarCrossref
  16. 16. J. K. Schoelz, P. Xu, S. D. Barber, D. Qi, M. L. Ackerman, G. Basnet, C. T. Cook, and P. M. Thibado, J. Vac. Sci. Technol. B 30, 033201 (2012). https://doi.org/10.1116/1.3701977 , Google ScholarCrossref
  17. 17. L. A. Hockett and S. E. Creager, Rev. Sci. Instrum. 64, 263 (1993). https://doi.org/10.1063/1.1144394 , Google ScholarScitation
  18. 18. R. Wiesendanger, Scanning Probe Microscopy and Spectroscopy: Methods and Applications (Cambridge University Press, 1994). Google ScholarCrossref
  19. 19. P. Xu, Y. Yang, S. D. Barber, M. L. Ackerman, J. K. Schoelz, D. Qi, I. A. Kornev, L. Dong, L. Bellaiche, S. Barraza-Lopez, and P. M. Thibado, Phys. Rev. B 85, 121406–R (2012). https://doi.org/10.1103/PhysRevB.85.121406 , Google ScholarCrossref
  20. 20. J. S. Bunch, A. M. van der Zande, S. S. Verbridge, I. W. Frank, D. M. Tanenbaum, J. M. Parpia, H. G. Craighead, and P. L. McEuen, Science 315, 490 (2007). https://doi.org/10.1126/science.1136836 , Google ScholarCrossref, ISI
  21. 21. F. F. Dall’Agnol and V. P. Mammana, Rev. Bras. Ensino Fís. 31, 3503 (2009). https://doi.org/10.1590/S1806-11172009005000004 , Google ScholarCrossref
  22. 22. P. Xu, Y. Yang, S. D. Barber, M. L. Ackerman, J. K. Schoelz, I. A. Kornev, S. Barraza-Lopez, L. Bellaiche, and P. M. Thibado, Phys. Rev. B 84, 161409–R (2011). https://doi.org/10.1103/PhysRevB.84.161409 , Google ScholarCrossref
  23. 23. N. Mohanty, M. Fahrenholtz, A. Nagaraja, D. Boyle, and V. Berry, Nano Lett. 11, 1270 (2011). https://doi.org/10.1021/nl104292k , Google ScholarCrossref
  24. 24. J. M. Yuk, J. Park, P. Ercius, K. Kim, D. J. Hellebusch, M. F. Crommie, J. Y. Lee, A. Zettl, and A. P. Alivisatos, Science 336, 61 (2012). https://doi.org/10.1126/science.1217654 , Google ScholarCrossref
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