ABSTRACT
Current-based deep level transient spectroscopy was used to study trap states in poly(3-hexylthiophene-2,5-diyl) (P3HT), [6,6]-phenyl-C61 butyric acid methyl ester (PCBM), and P3HT:PCBM blend. The obtained spectra showed traps of 87 meV activation energy in pure P3HT and 21 meV for PCBM. The blend shows a complex emission rate spectrum consisting of several different emission rate bands in the range of 0.1–30 s−1, yielding activation energies between about 30 meV and 160 meV.
The current work is supported by the Bundesministerium für Bildung und Forschung in the framework of the OPV Stability Project (Contract No. 03SF0334F). C.D. gratefully acknowledges the support of the Bavarian Academy of Sciences and Humanities. V.D.’s work at the ZAE Bayern is financed by the Bavarian Ministry of Economic Affairs, Infrastructure, Transport and Technology.
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