No Access Submitted: 18 August 1986 Accepted: 27 August 1986 Published Online: 04 June 1998
J. Chem. Phys. 85, 6455 (1986); https://doi.org/10.1063/1.451425
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  • Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125
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  • Maile E. Smith
  • Diane L. Lynch
  • Vincent McKoy
We report vibrational branching ratios and vibrationally resolved photoelectron angular distributions for resonant photoionization of the 5σ level of CO leading to X2Σ+CO+. These results were obtained using frozen‐core Hartree–Fock photoelectron continuum orbitals. These studies provide a clear quantitative picture of the role of the kσ shape resonance in the observed non‐Franck–Condon behavior and useful insight into the interplay between this shape resonance and a valence‐like autoionizing resonance around 23 eV.
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  1. © 1986 American Institute of Physics.